MnO2 Doped with Ag Nanoparticles and Their Applications in Antimicrobial and Photocatalytic Reactions
Creators
- 1. Department of Physics, Thiruvalluvar Government Arts College, Rasipuram 637401, Tamil Nadu, India
- 2. Department of Physics, Government Arts College for Women, Salem 636008, Tamil Nadu, India
- 3. Department of Physics, Government Arts College (Autonomous), Salem 636007, Tamil Nadu, India
- 4. Department of Botany and Microbiology, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
- 5. King Saud University
- 6. UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology Laboratories, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk Ridge, Pretoria P.O. Box 392, South Africa
- 7. Nanosciences African Network (NANOAFNET), Materials Research Group (MRG), iThemba LABS-National Research Foundation (NRF), 1 Old Faure Road, 7129, Somerset West P.O. Box 722, Western Cape Province, South Africa
Description
A wide range of nanoparticles have been produced for photocatalysis applications. Nonetheless, degrading organic dyes requires nanoparticles that are efficient and excellent. As a photocatalyst, pure manganese oxide (MnO2) was prepared via a sol–gel method using silver (Ag) nanoparticles of transition metal oxide. In addition to X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX), the crystal structure and elemental composition were analysed. According to XRD data, the transition metal of MnO2 oxide is highly pure and has a small crystallite size. The presence of functional groups was confirmed and clarified using Fourier-transform infrared spectra (FTIR). By irradiating the transition pure and doped MnO2 photocatalysts with visible light, the UV-vis, μ-Raman, and surface areas were determined. As a result, of using the photocatalysts with aqueous methylene blue (MB) solutions under visible light irradiation, the MnO2 doped with Ag nanoparticles demonstrated high degradation efficiencies and were utilised to establish heterogeneous photocatalysis dominance. In this paper, we demonstrate that the photocatalytic efficiency of transition metal oxides is exclusively determined by the particle size and surface area of nano-sized materials. Due to their high surface charge ratio and different surface orientations, have the highest photocatalytic efficiency. Generally, MnO2 doped with Ag nanoparticles is resistant to bacteria of both Gram-positive and Gram-negative types (B. sublittus and Escherichia coli). There is still a need for more research to be performed on reducing the toxicity of metal and metal oxide nanoparticles so that they can be used as an effective alternative to antibiotics and disinfectants, particularly for biomedical applications.
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DOI
10.3390/catal13020397
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References
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