Soft detoxification of chemical warfare agent simulants and pesticides under pressure.
- 1. CNRS, Normandie Université, UNIROUEN, INSA Rouen, COBRA laboratory, F-76000 Rouen, France. julien.legros@univ-rouen.fr.
- 2. Departamento de Química, Universidade Federal do Paraná (UFPR), CP 19081, CEP 81531-990, Curitiba, PR, Brasil.
- 3. Federal University of Paraná
Description
The neutralisation of structurally varied chemical warfare agent simulants (blister and nerve agents) and pesticides (Paraoxon) with the assistance of high pressure is reported. Chloroethyl amines and sulfides (nitrogen and sulfur mustards), phosphonothioates (V-series nerve agents) and phosphates (pesticide) readily react with simple nucleophilic scavengers (alcohols, amines) at P > 14 000 bar.
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Publication Details
Journal article
Journal:
Organic & biomolecular chemistry
Publisher:
Royal Society of Chemistry (RSC)
ISSN:
14770539
Volume:
20
Pages:
7604-7608
Funding
Financial Support
Centre National de la Recherche Scientifique
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Normandie Université
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European Regional Development Fund
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Conselho Nacional de Desenvolvimento Científico e Tecnológico
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior — Grant: 001
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L'Oreal USA
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Agence Nationale de la Recherche — Grant: Labex SynOrg (ANR-11-LABX-0029)
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Agence Nationale de la Recherche — Grant: graduate school for research XL-Chem (ANR-18-EURE-0020 XL CHEM)
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United Nations Educational, Scientific and Cultural Organization
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International Union of Pure and Applied Chemistry
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