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Journal article
Open Access
Combination of organocatalytic oxidation of alcohols and organolithium chemistry (RLi) in aqueous media, at room temperature and under aerobic conditions
Creators
- 1. University of Oviedo
- 2. EntreChem SL. Santo Domingo de Guzmán, Oviedo, Spain
- 3. University of Bern
Description
A tandem protocol to access tertiary alcohols has been developed which combines the organocatalytic oxidation of secondary alcohols to ketones followed by their chemoselective addition by several RLi reagents. Reactions take place at room temperature, under air and in aqueous solutions, a trio of conditions that are typically forbidden in polar organometallic chemistry.
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Publication Details
Journal article
Journal:
Chemical communications (Cambridge, England)
Publisher:
Royal Society of Chemistry
ISSN:
1364548x
Volume:
56
Pages:
8932-8935
Funding
Financial Support
Universität Bern
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Gobierno del Principado de Asturias — Grant: postdoctoral fellowship (Clarín-COFUND program)
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Ministerio de Economía y Competitividad — Grant: CTQ2016-75986-P
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Ministerio de Economía y Competitividad — Grant: CTQ2016-81797-REDC
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Ministerio de Economía y Competitividad — Grant: CTQ2017-88357-P
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United Nations Educational, Scientific and Cultural Organization — Grant: Green Chemistry for Life Grant
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References